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Research Without Boundaries
List of Strategic Areas:
RWB Welcome
Strategic Area: Advanced Materials
Strategic Area: Complex Systems and Networks
Strategic Area: Energy, Environment, and Sustainable Development
Strategic Area: Information, Computation, and Communication
Strategic Area: Nanomaterials, Nanodevices, and Nanoscience
Strategic Area: Systems Biology and Biomedical Engineering
List of Research Topics:
Flexible Electronic Materials
Materials Manufacturing
Materials Modeling
Nanoscale Polymer Composites
Photonic Materials
Advanced Materials
Nanoscale Polymer Composites
 
layered nanocomposite
This computergenerated simulation shows the building blocks of a layered nanocomposite. A copolymer is intercalated between mica-like layers of crystalline silicate. The layers of such a structure are only a nanometer–about three atoms–thick.
 

Emmanuel GiannelisA nano-sized polymer sphere impregnated with drugs and injected into a body where a complex nanoscale lattice will slowly release a drug before biodegrading into tissue is under development by Materials Science and Engineering Professor Emmanuel Giannelis. “In the old days, we had materials with properties that had compromises and tradeoffs. But here comes nanotechnology and nanocomposites, where if we pay attention to how these blocks are put together and dispersed at the nanometer scale, you can have structures with unique properties,” Giannelis says.

 
polydimethylsiloxane
Intercalated polydimethylsiloxane nanocomposite, 637 nm phase image
 
polystyrene and silicate
Transmission electron micrograph of (left) intercalated hybrid of polystyrene and a silicate and (right) another hybrid. Both show the polymer present between silicate layers.
 

Lynden ArcherLynden Archer, professor in Chemical and Biomolecular Engineering, studies the fluid dynamics of polymers. Some of his work is devoted to the problem of engineering materials that are in one way or another self-lubricating. These materials are promising for a variety of applications either where conventional lubricants cannot be used (such as jointreplacement surgery), or where their use is too costly (deployed space vehicles such as satellites, spacebased observatories, and permanently deployed space exploration equipment). Self-lubricated components also hold promise for preventing premature failure of microelectromechanical systems (MEMS).

“To design an effective self-lubricated material it is necessary that lubricant molecules possess high surface mobility even when chemically grafted to a rigid substrate,” Archer says. “This requirement must be balanced against the known tendency of substrates to slow down relaxation of liquids tethered to them.”

In studying the dynamics of polymeric and oligometric species near rigid substrates, Archer is particularly interested in determining how changes in molecular topology influence friction and drag of lubricant coatings tethered to surfaces.